Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas

This work is a multidisciplinary environmental study that provides new insights into the relationships between sediment-organic matter characteristics and polybrominated diphenyl ethers (PBDEs) concentration. The aim of the present multivariate study was to correlate factors influencing PBDEs accumu...

Descripción completa

Detalles Bibliográficos
Autores principales: Lana, Nerina Belén, Koch, Eduardo, D' Angelo, José Alejandro, Ciocco, Nestor Fernando, Altamirano, Jorgelina Cecilia
Formato: Artículo
Lenguaje:Inglés
Publicado: Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias 2014
Materias:
Acceso en línea:http://bdigital.uncu.edu.ar/7361
_version_ 1782341650389925888
author Lana, Nerina Belén
Koch, Eduardo
D' Angelo, José Alejandro
Ciocco, Nestor Fernando
Altamirano, Jorgelina Cecilia
author_facet Lana, Nerina Belén
Koch, Eduardo
D' Angelo, José Alejandro
Ciocco, Nestor Fernando
Altamirano, Jorgelina Cecilia
author_sort Lana, Nerina Belén
collection Repositorio
description This work is a multidisciplinary environmental study that provides new insights into the relationships between sediment-organic matter characteristics and polybrominated diphenyl ethers (PBDEs) concentration. The aim of the present multivariate study was to correlate factors influencing PBDEs accumulation in sediment by using principal component analysis (PCA). Organic matter studies by Fourier Transform-Infrared spectroscopy and physicochemical analyses (Total Organic Carbon, pH, electrical conductivity) of sediment samples were considered for PCA. Samples were collected from an artificial irrigation network on the Mendoza River irrigation areas. PCA provided a comprehensive analysis of the studied variables, identifying two components that explained 63% of the data variance. Those factors were mainly associated to organic matter degradation degree, which represent a new insight into the relationships between organic matter in sediments and PBDEs fate. In this sense it was possible to determine that not only the content but also the type of organic matter (chemical structure) could be relevant when evaluating PBDEs accumulation and transport in the environment. Typification of organic matter may be a useful tool to predict more feasible areas where PBDE, may accumulate, as well as sediment transportation capability.
format Artículo
id uncu-7361
institution Biblioteca Digital - UNCUYO
language Inglés
publishDate 2014
publisher Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias
record_format ojs
spelling uncu-73612016-04-27T11:44:05Z Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas Propiedades fisico-químicas de sedimentos condicionan la asociación de contaminantes : un estudio multivariado de éteres bifenilos polibromados en áreas de irrigación del Río Mendoza Lana, Nerina Belén Koch, Eduardo D' Angelo, José Alejandro Ciocco, Nestor Fernando Altamirano, Jorgelina Cecilia Sedimento Materia orgánica Bifenilos polibromados Sediment Organic matter Polybrominated biphenyls This work is a multidisciplinary environmental study that provides new insights into the relationships between sediment-organic matter characteristics and polybrominated diphenyl ethers (PBDEs) concentration. The aim of the present multivariate study was to correlate factors influencing PBDEs accumulation in sediment by using principal component analysis (PCA). Organic matter studies by Fourier Transform-Infrared spectroscopy and physicochemical analyses (Total Organic Carbon, pH, electrical conductivity) of sediment samples were considered for PCA. Samples were collected from an artificial irrigation network on the Mendoza River irrigation areas. PCA provided a comprehensive analysis of the studied variables, identifying two components that explained 63% of the data variance. Those factors were mainly associated to organic matter degradation degree, which represent a new insight into the relationships between organic matter in sediments and PBDEs fate. In this sense it was possible to determine that not only the content but also the type of organic matter (chemical structure) could be relevant when evaluating PBDEs accumulation and transport in the environment. Typification of organic matter may be a useful tool to predict more feasible areas where PBDE, may accumulate, as well as sediment transportation capability. Este trabajo es un estudio ambiental multidisciplinario que proporciona nuevos conocimientos sobre las relaciones entre las características de la materia orgánica presente en sedimentos y la concentración de éteres difenilos polibromados (PBDEs). Se buscó correlacionar características físico-químicas de muestras de sedimento usando análisis de componentes principales (PCA). Las muestras fueron caracterizadas por su contenido de materia orgánica total, pH y conductividad eléctrica. Adicionalmente, la materia orgánica de dichas muestras fue analizada mediante Espectroscopía de Infrarrojos con Transformada de Fourier. Las muestras fueron colectadas en diferentes canales de irrigación de la red alimentada por el Río Mendoza. El PCA proporcionó un análisis exhaustivo de las variables estudiadas y su vinculación, resultando dos componentes que explicarían el 63% de la varianza de los datos. Ambas componentes se asociaron al estado de degradación de la materia orgánica. En este sentido, fue posible determinar que tanto la cantidad de materia orgánica de los sedimentos como el tipo (estructura química) de materia orgánica estarían condicionando la acumulación y el transporte de PBDEs en el ambiente. A partir de los resultados es posible proponer a la tipificación de la materia orgánica de sedimento como herramienta útil y efectiva para predecir áreas donde es más factible que se acumule PBDE, así como la capacidad de transporte en los sedimentos. Fil: Lana, Nerina Belén. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales Fil: Koch, Eduardo. Fil: D' Angelo, José Alejandro. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales Fil: Ciocco, Nestor Fernando. Fil: Altamirano, Jorgelina Cecilia. Instituto Argentino de Nivología, Glaciología y Ciencias Ambientales Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias 78 Revista de la Facultad de Ciencias Agrarias Vol. 46, no. 2 Revista de la Facultad de Ciencias Agrarias, Vol. 46, no. 2 2014-12-01 eng Inglés http://bdigital.uncu.edu.ar/7347 info:eu-repo/semantics/openAccess http://creativecommons.org/licenses/by/2.5/ar/ article info:ar-repo/semantics/artículo info:eu-repo/semantics/article info:eu-repo/semantics/publishedVersion application/pdf Universidad Nacional de Cuyo. Facultad de Ciencias Agrarias http://bdigital.uncu.edu.ar/7361
spellingShingle Sedimento
Materia orgánica
Bifenilos polibromados
Sediment
Organic matter
Polybrominated biphenyls
Lana, Nerina Belén
Koch, Eduardo
D' Angelo, José Alejandro
Ciocco, Nestor Fernando
Altamirano, Jorgelina Cecilia
Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas
title Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas
title_full Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas
title_fullStr Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas
title_full_unstemmed Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas
title_short Sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the Mendoza River irrigation areas
title_sort sediment physicochemical properties condition pollutant association : a multivariate study of polybrominated diphenyl ethers on the mendoza river irrigation areas
topic Sedimento
Materia orgánica
Bifenilos polibromados
Sediment
Organic matter
Polybrominated biphenyls
url http://bdigital.uncu.edu.ar/7361